Synthesis, crystal structure, and alkali metal picrate extraction capabilities of molecular clips based on diphenylglycoluril and benzocrown ethers
β Scribed by Tatiana Yu. Bogaschenko; Alexander Yu. Lyapunov; Leonid S. Kikot'; Alexander V. Mazepa; Mark M. Botoshansky; Marina S. Fonari; Tatiana I. Kirichenko
- Book ID
- 113929441
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- French
- Weight
- 989 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0040-4020
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The syntheses of novel cage-functionalized crown ethers, It-t3, that contain one or more pyridyl units are reported. The results of alkali metal picrate extraction experiments performed by using 1 i and 12 are compared with those obtained by using the corresponding model (non-cage) crown ethers. Cag
The synthesis of a series of cage-functionalized bis(monoazacrown) ethers and bis(diazacrown) ethers is described. Alkali metal picrate extraction profiles have been determined for several members of this novel series of ionophores. The increased level of preorganization achieved when a cagefunction
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