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Synthesis, Chirality and Complexation Phenomena of Two Diastereoisomeric Dinuclear Lanthanide(III) Complexes

✍ Scribed by Benjamin S. Murray; David Parker; Cidália M. G. dos Santos; Robert D. Peacock


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
836 KB
Volume
2010
Category
Article
ISSN
1434-1948

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A dinuclear manganese complex ([Mn 2 L(µ-OAc) 2 ]PF 6 ) has been synthesized, where L is the trianion of 2,6-bis{[(2-hydroxy-3,5-di-tert-butylbenzyl)(2-pyridylmethyl)amino]-methyl}-4-methylphenol, a ligand with three phenolate groups. The two pseudo-octahedrally coordinated Mn ions are bridged via t