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Synthesis, chemical reactions and redox properties of ruthenium complexes of a tetradentatebischelating ligand, 2,2′-azobis(pyridine)

✍ Scribed by Partha Majumdar; Alok K Deb; Sreebrata Goswami


Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1998
Tongue
English
Weight
507 KB
Volume
110
Category
Article
ISSN
0253-4134

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## Abstract The synthesis of a number of new 2,2′‐bipyridine ligands functionalized with bulky amino side groups is reported. Three homoleptic polypyridyl ruthenium (II) complexes, [Ru(L)~3~]^2+^ 2(PF~6~^−^), where L is 4,4′‐dioctylaminomethyl‐2,2′‐bipyridine (Ru4a), 4,4′‐didodecylaminomethyl‐2,2′‐