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Synthesis, characterization, X-ray structure and spectroscopic study of platinum(II) complexes with tridentate diazene ligands having O,N,S donor set

✍ Scribed by Acharya, Suvra; Kejriwal, Ambica; Biswas, Achintesh Narayan; Das, Purak; Neogi, Debatra Narayan; Bandyopadhyay, Pinaki


Book ID
122830653
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
835 KB
Volume
394
Category
Article
ISSN
0020-1693

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The six-step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(I1) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. Th