Synthesis, Characterization, Thermodynamic and Kinetic Properties of a New Series of Dinuclear PtII Complexes
✍ Scribed by Hakan Ertürk; Ralph Puchta; Rudi van Eldik
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 510 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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Dinuclear Cu II complexes, [Cu 2 (salophen) 2 ] (1) and [Cu 2 (salen) 2 ] (2), with Schiff bases derived from salicylaldehyde and o-phenylenediamine (ophen) or ethylenediamine (en) were synthesized and characterized. They exhibit square-planar geometry with CuN 2 O 2 coordination, where the dianioni
## Abstract A series of dinuclear platinum^II^ complexes of the type [{__trans__‐Pt(H~2~O)(NH~3~)~2~}~2~‐NH~2~(CH~2~)~n~H~2~N]^4+^ (where __n__ = 2, 3, 4, and 6) were synthesized to investigate the influence of the bridging diamine linker on the reactivity of the platinum centers. The p__K__~a~ val