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Synthesis, characterization, spectroscopy, magnetism and X-ray structures of red and green Cu(II) chloride adducts with bis(2-benzimidazolyl)propane

✍ Scribed by Gerard A. van Albada; Wilberth J.J. Smeets; Anthony L. Spek; Jan Reedijk

Book ID: 108331786
Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 140 KB
Volume: 288
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(99)00074-2

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The ligand bis(2-benzimidazolyl)propane coordinates to Ni II with a zero-field splitting parameter D (-14.3 cm -1 ) and a ferromagnetic exchange between the Ni ions in the dinuclear with chloride as an anion, thereby forming a dinuclear compound with the formula: [NiCl 2 (tbz) 2 ] 2 (C 2 H 6 O) 2 .

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