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Synthesis, characterization of carbon-bridged Bis(phenolate) neodymium complexes and their catalytic activity for ring-opening polymerization of cyclic esters

โœ Scribed by Zhenhua Liang; Xufeng Ni; Xue Li; Zhiquan Shen


Book ID
113661887
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
449 KB
Volume
14
Category
Article
ISSN
1387-7003

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## Abstract Two methods to synthesize homoleptic guanidinate lanthanide complex are described. The samarium guanidinate complex [Sm{Ph~2~NC(NCy)~2~}~3~]ยท2C~7~H~8~ (1) can be synthesized by the metathesis reaction of lithium guanidinate with anhydrous samarium trichloride in a 3:1 molar ratio. The a