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Synthesis, Characterization, Crystal Structures and Thermal and Fluorescence Studies of Dinuclear and Polymeric Silver(I) Complexes of 5,5-Diethylbarbiturate with 2,5-Dimethylpyrazine and Piperazine Involving Ag–Ag Interactions

✍ Scribed by Eda Soyer; Fatih Yilmaz; Veysel T. Yilmaz; Orhan Buyukgungor; William T. A. Harrison

Publisher
Springer
Year
2010
Tongue
English
Weight
463 KB
Volume
20
Category
Article
ISSN
1053-0495

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Synthesis and crystal structure of silver and argentate complexes of mixed halocarborane anions, (C5H5N)2Ag(1-HCB11Br5I6)(C5H5N) and [{(CH3CN)4Ag3}{Ag(CB11I5Br6)2}]n
✍ Chi-Wing Tsang; Qingchuan Yang; Thomas C. W. Mak; Zuowei Xie 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 217 KB 👁 1 views

## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Single‐crystal X‐ray analyses indicate that the CB~11~I~5~Br~6~^2−^ dianion has a signi