## Reactions of PhAsCl 2 with BrMg(CH 2 ) n MgBr (n = 4 or 5) in THF gave phenylarsacycloalkanes as colourless oily liquids which could be distilled under vacuum. Treatment of PhAs C (CH 2 ) n with MCl 2 (RCN) 2 (M = Pd or Pt; R = Ph or Me) afforded mononuclear complexes, [MCl 2 {PhAs C (CH 2 ) n
✦ LIBER ✦
Synthesis, characterization and X-ray structure of N-2-pyridylmethylidene-1-phenylethylamine–PdCl2 complexes
✍ Scribed by Anatoly Mishnev; Irina Iovel; Juris Popelis; Ilze Vosekalna; Edmunds Lukevics
- Book ID
- 108346643
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 116 KB
- Volume
- 608
- Category
- Article
- ISSN
- 0022-328X
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Complexes of the type M{Ph 2 P(CH 2 ) n N CHC 6 H 4 -o-OH} 2 (n= 3, 4 and M= cis-and trans-PdCl 2 , cis-PtCl 2 , cis,cis,trans-RuCl 2 (CO) 2 ) have been synthesized by the reactions of the ligands with the appropriate metal precursors. All of the complexes are obtained in high yields, and, in all of