Synthesis, Characterization, and the Platinum-Catalyzed Ring-Opening Polymerization and Stereoselective Dimerization of Silicon-Bridged [1]Ferrocenophanes with Acetylenic Substituents
β Scribed by Berenbaum, Andrea; Lough, Alan J.; Manners, Ian
- Book ID
- 127259408
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 165 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
Photocontrolled living anionic ring-opening polymerization (ROP) of strained silicon-bridged [1] 3) with 3,3,3-trifluoropropyl, heptadecafluoro-1,1,2,2-tetrahydrodecyl, and pentafluorophenylpropyl hydrofluorocarbon substituents, respectively, on silicon, have been explored. Thus well-defined fluorin
## Abstract The transition metalβcatalyzed ringβopening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fcβ=βFe(__Ξ·__βC~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^