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Synthesis, characterization, and reverse-micellar studies of some N-substituted derivatives of 6-amino-6-deoxy-1,2-O-isopropylidene-d-glucose

✍ Scribed by Lalit Sharma; Serjinder Singh

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 345 KB
Volume: 270
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(94)00007-3

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✦ Synopsis

Dry heating of N-substituted hexadecylamines with 5,6-anhydro-l,2-O-isopropylidene-a-Dglucofuranose afforded glucose-based nonionic surfactants having a tertiary amino group linked to C-6 of the glucose moiety. These surfactants were tested for the solubilization of the L-amino acids tryptophan, tyrosine, phenylalanine, and cysteine in n-hexane. Reverse-micellar measurements revealed that (6,6'-hexadecylimino)bis(6-deoxy-l,2-O-isopropylidene)-a-D-glucofuranose is the most effective surfactant.

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