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Synthesis, Characterization, and Reactivity of trans-Ir(PR3)2(CO)(NHR'), where R = Me and Et and R' = Ph and But

✍ Scribed by Rahim, Marufur; Bushweller, C. Hackett; Ahmed, Kazi J.


Book ID
126899984
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
786 KB
Volume
13
Category
Article
ISSN
0276-7333

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The novel (ferriomethyl)-substituted silanols C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)OH [R = H, RЈ = Me (4a), Ph (4b); R = Me, RЈ = Me (4c)] are obtained by hydrolysis of the chloro(ferriomethyl)silanes C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)Cl [R = H, RЈ = Me (3a), Ph (3b); R = Me, RЈ = Me (3c)] in the presence