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Synthesis, characterization and reactivity of the molybdenum(VI) complex [MoCl(NAr)2(CH2CMe2Ph)] (Ar=2,6-Pri2C6H3)

✍ Scribed by Vernon C. Gibson; Carl Redshaw; Gary L.P. Walker; William Clegg; Mark R.J. Elsegood

Book ID: 108187767
Publisher: Elsevier Science
Year: 2004
Tongue: English
Weight: 382 KB
Volume: 689
Category: Article
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2003.10.020

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## Abstract The very bulky phenols Ar\*OH (1) and Ar′OH (2), where Ar\* = C~6~H~3~‐2,6‐Trip~2~ (Trip = C~6~H~2~‐2,4,6‐__i__Pr~3~) and Ar′ = C~6~H~3~‐2,6‐Dipp~2~ (Dipp = C~6~H~3~‐2,6‐__i__Pr~2~), as well as their lithium and sodium derivatives (LiOAr\*)~2~ (3), (LiOAr′)~2~ (4) and (NaOAr\*)~2~ (5) h