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Synthesis, characterization and properties of microporous lanthanide silicates: K8Ln3Si12O32NO3·H2O (Ln = Eu, Tb, Gd, Sm)

✍ Scribed by Xi Wang; Jiyang Li; Guangmei Wang; Yide Han; Tan Su; Yi Li; Jihong Yu; Ruren Xu

Book ID
113913725
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
767 KB
Volume
12
Category
Article
ISSN
1293-2558

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Synthesis and structure of two lanthanid
Synthesis and structure of two lanthanide complexes with isonicotinic acid N-oxide (HL): [Ln(L)2(H2O)4]n·(NO3)n·n(H2O) (Ln = Sm or Tb)
✍ Mohamed A.S. Goher; Franz A. Mautner 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 206 KB

Two new lanthanide complexes of isonicotinic acid N-oxide (HL), namely [Ln(L) 2 (H 2 O) 4 ] n AE(NO 3 ) n AEn(H 2 O) for Ln = Sm or Tb, have been synthesized and characterized by spectroscopic and crystallographic methods. IR spectra suggest that isonicotinic acid N-oxide acts as a O,O 0 -bidentate