LE, Xue-Yi" p"(%%X) YANG, Guang*(&jk) FENG, Xiao-Long'(~~~l&) JI, Liang-Nian*(it%W 'De-r~ of Applied Chemistry, College of Sciences, South-China Ag~iculturd University , Guangzhou , cucmgdow 510642, China bDepart.l..t of Chemistry, Zhngshun University, Guangzhou , Guangdong 510275, China 'Center of M y s i s and Measurement, Z h n g s h University, GuMgzhou, Guanghng 510275, China
'Ibe complex [Cu( L-phe)(TATp)(~O)Ic1o,~O.5H~O has been synthesizes and investigated by elemental analysis, mdar conductivity, spectroscopic and X-ray diffkacfioo methods, where TATP = 1,4,8, Ptetraazetriphenylene and L-phe = Lphenylaninate group. The complex aystallizg in the triclinic space group PI with two molecules in a unit cell of dimensions a=O.mO(l), b=1.0190(2), c=2.1430(4), a = 97.50 ( 1 ) ' . 8=95.33(3)', y = 102.85(1)', V = 1.1998(4) d , R,=0.0360, wRz=0.0400. The crystal conhim two inde-Cu2, having essentially the same distorted square-pyramidal stntcture, where each Cu(n) ion coordinates two nitrogen atoms of TATP and the amin0 nitrogen and carboxylate oxygen atom of L-Phe in the equatorial positions and one water oxygen at an axial position. pendent [Cu(L-Phe)(TATP)(&O)I* c ~m p l e x e ~ Cul and Keywords copped JI) complex, crystal structure 1 , 4 , 8 , 9-Tetnuuatriphenylene, L-phenylaninate , 'A synthesis ofthe CU(I1) complex TAW (1 m 0 1 ) and CU( C1O4),*6H2O (1 mm01)
were dissolved in 25 mL of 80% ( V / V > methanol-water