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Synthesis, characterization and magnetic properties of some LnBO3 (Ln ≡ Pr, Sm, Eu AND Yb) compounds

✍ Scribed by Y. Laureiro; M.L. Veiga; F. Fernández; R. Saez-Puche; A. Jerez; C. Pico


Book ID
116018145
Publisher
Elsevier Science
Year
1991
Weight
388 KB
Volume
167
Category
Article
ISSN
0022-5088

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Depending on the ionic radius of the rare earth ions, orthoborates exhibit three di4erent crystalline forms noted LnBO 3 and H-LnBO 3 . A comparative study of the stability relationship of H-LnBO 3 borate (Ln ‫؍‬ La, Nd, Sm, and Eu) versus the temperature and synthesis method (solid state reaction a

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Magnetic properties of ordered perovskites Ba 2 LnIrO 6 (Ln ‫؍‬ Sm, Eu, Gd, and Yb) are reported. Their magnetic susceptibilities were measured from 2 to 350 K. The 151 Eu MoK ssbauer spectrum of Ba 2 EuIrO 6 and the electronic paramagnetic resonance (EPR) spectrum of Ba 2 GdIrO 6 were measured at r