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Synthesis, Characterization, and Magnetic Properties of New Rh(III) Compounds with the K4CdCl6Structure-Type:Sr3MRhO6(M=Sm, Eu, Tb, Dy, Ho, Er, and Yb)

✍ Scribed by Ralph C Layland; Shalawn L Kirkland; Hans-Conrad zur Loye

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 372 KB
Volume: 139
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.1998.7809

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✦ Synopsis

The compounds Sr 3 MRhO 6 (M ‫؍‬ Sm, Eu, Tb, Dy, Ho, Er, and Yb) have been synthesized and structurally characterized by Rietveld refinement of powder X-ray diffraction data in the space group R3 c; Z ‫؍‬ 6. The lattice parameters for the series were found to be a ‫؍‬ 9.78570(7) and c ‫؍‬ 11.4811(1) A > , a ‫؍‬ 9.7837(1) and c ‫؍‬ 11.4421(2) A > , a ‫؍‬ 9.7662(2) and c ‫؍‬ 11.3812(4) A > , a ‫؍‬ 9.7627(2) and c ‫؍‬ 11.3451(2) A > , a ‫؍‬ 9.7591(2) and c ‫؍‬ 11.3159(2) A > , a ‫؍‬ 9.7557(2) and c ‫؍‬ 11.2919(3) A > , and a ‫؍‬ 9.7390(2) and c ‫؍‬ 11.2501(3) A > , for

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