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Synthesis, characterization, and fluorescence phenomena of 1-naphthoxy and 1-naphthylamino substituted cyclotriphosphazenes

✍ Scribed by Fatih Aslan; Oǧuzhan Halcı; Mustafa Arslan

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
189 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The reactions of hexachlorocyclotriphosphazene N~3~P~3~Cl~6~ (1) with 1‐naphthol and 1‐naphthylamine have been examined. The reaction of 1 with sodium 1‐naphthoxy gave the hexakis(1‐naphthoxy)cyclotriphosphazene (2) in high yield. Geminal 2,2‐di(1‐naphthylamino)‐4,4,6,6‐tetrachlorocyclotriphosphazene (3) was obtained from the reaction of 1 with 1‐naphthylamine. The structures of phosphazene derivatives were defined by elemental analysis, FTIR, UV‐‐visible, and ^1^H, ^13^C, ^31^P NMR spectroscopy. The fluorescence intensity of the compounds was measured in THF and CH~2~Cl~2~. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:158–162, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20400

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