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Synthesis, characterization and electronic properties of some hetero-arylene vinylene oligomers

✍ Scribed by Johan F.A. Van Der Looy; Gerd J.H. Thys; Pieter E.M. Dieltiens; Daniël De Schrijver; Christian Van Alsenoy; Herman J. Geise

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
855 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

The synthesis and characterization is reported of six 2,5-distyryl-heteroarylenes (BXB compounds) and 1,4-bis{ 2-(heteroaryl-2-yl) ethenyl}benzenes (XBX compounds) containing the thienyl, furanyl or N-methylpyrryl as the heteroarylene moiety. By means of NMR and UVNis spectroscopy the electronic structure was probed. Quantum mechanical calculations using the semiempirical CNDO/S-CI approach rationalize the experimental findings and support the peak assignments.

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