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Synthesis, Characterization and Electrochemistry of the Novel Dawson-Type Tungstophosphate [H4PW18O62]7- and First Transition Metal Ions Derivatives.

✍ Scribed by Israel-Martyr Mbomekalle; Bineta Keita; Yu Wei Lu; Louis Nadjo; Roland Contant; Nebebech Belai; Michael T. Pope


Publisher
John Wiley and Sons
Year
2004
Weight
126 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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The complexes formed by [(1)-2,3-P 2 Mo 2 W 15 O 61 ] 10-with vanadium(IV), manganese(II), cobalt(II), nickel(II), copper(II), and zinc(II) were synthesized. They were characterized by elemental analysis, IR, UV/Vis and 31 P NMR spectroscopy. Their electrochemical studies are complemented by those o