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Synthesis, Characterization and Degradation of Poly(silyl ester)s

✍ Scribed by Wang, Min; Weinberg, Jennifer M.; Wooley, Karen L.


Book ID
127391650
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
193 KB
Volume
31
Category
Article
ISSN
0024-9297

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Geminal poly(silyl ester)s: Highly labil
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Geminal silyl ester linkages were used for the backbone construction of linear polymers, which exhibit rapid cleavage in the presence of atmospheric water. A series of poly(gem-silyl ester)s with two ester groups flanking each silicon atom were synthesized, in order to probe the effects of different

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## Abstract Two series of thermoplastic poly(ester–siloxane)s, based on poly(dimethylsiloxane) (PDMS) as the soft segment and poly(butylene terephthalate) as the hard segment, were synthesized by two‐step catalyzed transesterification reactions in the melt. Incorporation of soft poly(dimethylsiloxa