Synthesis, Characterization and Degradation of Poly(silyl ester)s
β Scribed by Wang, Min; Weinberg, Jennifer M.; Wooley, Karen L.
- Book ID
- 127391650
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 193 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
Geminal silyl ester linkages were used for the backbone construction of linear polymers, which exhibit rapid cleavage in the presence of atmospheric water. A series of poly(gem-silyl ester)s with two ester groups flanking each silicon atom were synthesized, in order to probe the effects of different
## Abstract Two series of thermoplastic poly(esterβsiloxane)s, based on poly(dimethylsiloxane) (PDMS) as the soft segment and poly(butylene terephthalate) as the hard segment, were synthesized by twoβstep catalyzed transesterification reactions in the melt. Incorporation of soft poly(dimethylsiloxa