Pyrazolato Metal Complexes β Synthesis,
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G. Attilio Ardizzoia; Girolamo La Monica; Angelo Maspero; Norberto Masciocchi; M
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Article
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1999
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John Wiley and Sons
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English
β 334 KB
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By treating [(CO) 3 Re(Hpz) 2 (pz)] (Hpz = pyrazole) with complexes 1a-c with cyclohexyl isocyanide (c-C 6 H 11 NC) afforded the derivatives {(CO) 3 Re(pz) 3 [M(c-C 6 H 11 NC)] 2 } (2a-[Cu(CH 3 CN) 4 ]BF 4 , AgNO 3 , or [Au(tht)Cl] (tht = tetrahydrothiophene) in acetonitrile in the presence of Et 3