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Synthesis, characterization and catalytic testing of SAPO-18, MgAPO-18, and ZnAPO-18 in the MTO reaction

✍ Scribed by Rune Wendelbo; Duncan Akporiaye; Anne Andersen; Ivar M. Dahl; Helle B. Mostad


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
664 KB
Volume
142
Category
Article
ISSN
0926-860X

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Quantum chemical modeling of chiral cata
✍ Vesa Nevalainen πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 502 KB

Properties of Lewis acidic oxazaborolidines 1 were investigated by means of ab initio MO methods (RHF, Ksulfonylated 1,3,2-oxazaborolidine 1' as a model). Energies of the coordination of aldehydes to 1 were estimated by using formaldehyde and acrolein adducts of 1' as models. Energies (MP2/6-31G//6-