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Synthesis, characterization and catalytic applications of rhodium(I) organometallics with substituted tertiary phosphines

✍ Scribed by Puri Usha Rani; P. Muralidhar Reddy; Kanne Shanker; Vadde Ravinder

Book ID: 106547381
Publisher: Springer
Year: 2007
Tongue: English
Weight: 280 KB
Volume: 33
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-007-9030-2

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru