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Synthesis, characterization and catalytic activity of some organolanthanides in ethylene polymerization

✍ Scribed by Vitor Lavini; Alessandra de Souza Maia; Ícaro Sampaio Paulino; Ulf Schuchardt; Wanda de Oliveira


Book ID
108495858
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
61 KB
Volume
4
Category
Article
ISSN
1387-7003

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Five new hetero-bimetallic metallocene complexes were synthesized by the reaction of RCpTiCl 3 and a Si-bridged zirconocene complex in refluxing toluene. They were all well characterized. These complexes activated with methylaluminoxane (MAO) are highly active catalysts for the polymerization of eth