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Synthesis, characterization and catalytic activity of polynuclear manganese complexes of 2,5-dihydroxyterephthalaldehyde for epoxidation of olefins with H2O2
β Scribed by R. Krishnan; S. Vancheesan
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 167 KB
- Volume
- 157
- Category
- Article
- ISSN
- 1381-1169
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π SIMILAR VOLUMES
Two symmetrical acetylacetone-based Schiff bases were immobilized on a silica surface by grafting and sol-gel procedure. The corresponding supported manganese complexes were prepared and evaluated as heterogeneous catalysts for alkene epoxidation with H 2 O 2 . These heterogeneous catalysts show rem
The use of [Mn 2 O 3 (tmtacn) 2 ](PF 6 ) 2 (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane) in combination with glyoxylic acid methylester methyl hemiacetal (GMHA) results in a highly active and hydrogen peroxide efficient catalyst for the epoxidation of olefins as well as the first homogeneous cata