## Abstract Amphiphilic ABCBA pentablock copolymers based on PVP, PS, and PDMS were synthesized using a combination of ATRP and RAFT polymerizations. The PVP__‐block‐__PS__‐block‐__PDMS__‐block‐__PS__‐block‐__PVP pentablock copolymer was characterized using a variety of chromatography and spectrosc
Synthesis, characterization, and application of PVP/PAM copolymer
✍ Scribed by K. S. Huang; C. N. Hsiao; Y. H. Nien; J. M. Lin
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 88 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The aim of this study was to synthesize copolymers from N‐vinyl‐2‐pyrrolidinone (NVP) and acrylamide (AM) at different molar ratios and investigate the influence of the different ratios on copolymers' properties. How copolymers affect the washing and stain‐repelling effects of carbon black, PET, Nylon, or cotton fabrics was also evaluated. Results show that as the AM content increased, the copolymers decomposed more slowly by heat, indicating better heat stability. In addition, copolymers were characterized as lowering surface tension and having excellent dispersing ability, low foaming properties, and excellent acid and alkaline resistance. The addition of copolymer can produce stain‐repelling effects against carbon black, PET, or Nylon‐colored fabrics. It was also determined that fabrics' stain‐repelling effects have no significant relationship to the NVP/AM molar ratio in copolymer synthesis. However, carbon black has better stain repellence as the AM monomer content increased. Two types of stain repellence gave better results when a higher concentration of copolymer was added. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 2006
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