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Synthesis, Characterization, and Activity in Ethylene Polymerization of Silica Supported Cationic Cyclopentadienyl Zirconium Complexes

✍ Scribed by Millot, Nicolas; Soignier, Sophie; Santini, Catherine C.; Baudouin, Anne; Basset, Jean-Marie


Book ID
126240612
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
217 KB
Volume
128
Category
Article
ISSN
0002-7863

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Eight zirconocene dichloride complexes are described that contain an alkyl or silylalkyl substituent with a fluorenyl end group on the cyclopentadienyl ring. Also, a bridged cyclopentadienyl indenyl metallocene complex with a fluorenyl terminated alkyl substituent is reported. These complexes were a