## Abstract A series of chloridoruthenium(II) complexes bearing the tripodal ligand tris(pyrazolyl)borate (Tp), the water‐soluble cage phosphane 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and its __N__‐boranyl adduct PTA(BH~3~), together with PPh~3~, have been synthesised. The corresponding monohydrido
✦ LIBER ✦
Synthesis, characterisation and crystal structures of new water-soluble 1-alkanaminedicarbonyl(η5-cyclopentadienyl)ruthenium(II) tetrafluoroborate complex salts
✍ Scribed by Nyawade, Eunice A.; Friedrich, Holger B.; Omondi, Bernard
- Book ID
- 122130139
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 918 KB
- Volume
- 415
- Category
- Article
- ISSN
- 0020-1693
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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3