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Synthesis, cation distribution and crystal structure of the spinel oxides MnGaxFe1−xCrO4 by neutron diffraction

✍ Scribed by A.K.M. Zakaria; M.A. Asgar; S.G. Eriksson; F.U. Ahmed; S.M. Yunus; A.K. Azad


Book ID
108239337
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
156 KB
Volume
385-386
Category
Article
ISSN
0921-4526

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The alkali sodium ferrate (IV) Na 4 FeO 4 has been prepared by solid-state reaction of sodium peroxide Na 2 O 2 and wustite Fe 1؊x O, in a molar ratio Na/Fe‫,4؍‬ at 4003C under vacuum. Powder X-ray and neutron di4raction studies indicate that Na 4 FeO 4 crystallizes in the triclinic system P؊1 with