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Synthesis, catalytic activity and redox properties of palladium(0) complexes with 15-membered triolefinic macrocyclic ligands containing one, two or three ferrocenyl groups

✍ Scribed by Antoni Llobet; Ester Masllorens; Marcial Moreno-Mañas; Anna Pla-Quintana; Montserrat Rodrı́guez; Anna Roglans


Book ID
104250455
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
75 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


A series of 15-membered triolefinic macrocycles containing ferrocenyl groups and their palladium(0) complexes have been synthesized and characterized. Their catalytic activity has been demonstrated in Suzuki-type cross-coupling and in the Heck reaction. Their redox properties have been investigated by means of cyclic voltammetry.