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Synthesis, catalytic activity and recycle of novel dimeric salen-Mn(III) complexes in asymmetric epoxidation

✍ Scribed by Liu Xinwen; Tang Ning; Liu Weisheng; Tan Minyu


Book ID
108211257
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
96 KB
Volume
212
Category
Article
ISSN
1381-1169

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Catalytic and asymmetric epoxidation of
✍ Pekka PietikΓ€inen πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 311 KB

Catalytic epoxidation of two unfunctionalized alkenes, 1,2\_dihydronaphthalene and tranx-e-methylstyrene, is reported using achiral and chirol (Salen)Mn(III) complexes l-3 together with a nitrogen heterocycle as axial ligand in the presence of 30 %I aqueous hydrogen peroxide as oxidant. Typically, t