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Synthesis applications of aza-cope rearrangements. Stereoselective synthesis of trans-alkyl-cis-3a-aryloctahydroindolones.

✍ Scribed by Larry E Overman; Leah T Mendelson; Lee A Flippin

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 215 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87444-4

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✦ Synopsis

The reaction of both cis-and trans-2-amino-l-(l-phenylvinyl)cyclopentanols with aldehydes affords trans-2-alkyl-cis-3a-aryl-4-oxo-octahydro indoles stereoselectively.

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