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Synthesis and α-alkylation of 1-menthylphosphetane sulfide

✍ Scribed by Angela Marinetti; François-Xavier Buzin; Louis Ricard


Book ID
104207676
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
467 KB
Volume
53
Category
Article
ISSN
0040-4020

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The readily available aminomethylsilanes can be utilized to prepare the less available ␣alkyl-␣-aminosilanes. Versatile t-butoxycarbonyl (Boc) derivatives can be metalated between nitrogen and silicon, and then alkylated by an electrophile at this position. Two alternative procedures were also devel