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Synthesis and x-ray structure of the first lanthanide 2-mercaptopyridine n-oxide complex, tris-(1-hydroxy-2(1H)-pyridinethionato-o, s) bis [sulfinylbis (methane)] samarium(III)

✍ Scribed by Ren-Gen Xiong; Jing-Lin Zuo; Xiao-Zeng You; Xiao-Ying Huang


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
227 KB
Volume
15
Category
Article
ISSN
0277-5387

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✍ Josefina Díez; M. Pilar Gamasa; José Gimeno; Yolanda Rodríguez; Santiago García- 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_