metacyclophane 4 is thefirstofitskind to erystatlize with both bridges in the pseudo-boafconformation. Anumber ofotberunusual features arealso apparent in the crystal structure,noneofwhich arepredicted byAMlorabiniriocatcntations. 01997 Elsevier Science Ltd. 2,1l-Dithia[3.3]metacyclophanes areprom
β¦ LIBER β¦
Synthesis and x-ray structure of 2,11-dithia-6,15-dimethyl[3.3]metacyclophane
β Scribed by Tze -Lock Chan; Chi -Kin Chan; Kam -Wah Ho; John S. Tse; Thomas C. W. Mak
- Book ID
- 105168322
- Publisher
- Springer
- Year
- 1977
- Tongue
- English
- Weight
- 323 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1572-8854
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## Abstract Synthesis and Xβray structural analysis of __anti__β[3.3]metacyclophaneβ2,11βdione quinhydrone dimethyl ether (3) are described. The formation of __anti__β3 starting from __syn__β9 may be ascribed to the __synβanti__ isomerization of the __syn__βquinhydrone 17 according to a benzoquinon
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