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Synthesis and X-ray Structure Determination of tert-Butylhydrazinium Azide and N,N,N-Trimethylhydrazinium Azide

✍ Scribed by Tassilo Habereder; Anton Hammerl; Gerhard Holl; Thomas M. Klapötke; Jörg Knizek; Heinrich Nöth

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 233 KB
Volume: 1999
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199905)1999:5<849::aid-ejic849>3.0.co;2-a

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✦ Synopsis

tert-Butylhydrazinium azide [tBuNH 2 NH 2 ] + [N 3 ] -(1) was azide with N,N,N-trimethylhydraziniumiodide. Both were characterized by X-ray structural analysis, IR, Raman, and prepared in a high yield reaction from tert-butylhydrazine and HN 3 . N,N,N-Trimethylhydrazinium azide [NH 2 N-multinuclear ( 1 H, 13 C, 14 N) NMR spectroscopy. (CH 3 ) 3 ] + [N 3 ] -(2) was prepared from the reaction of silver [ ] Crystal structure analysis.

ted to the non-protonated nitrogen of the tert-butylhydrazi-

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