The coordination behaviour of 2,6-disilyl-substituted characterized. The formation of 6 results from a [4 + 2] cycloaddition between one alkynyl group of each phosphinine phosphinines towards gold(I) has been examined. The reaction of the bis(trimethylsilyl)phosphinine 1 with [AuCl(SMe 2 )] gives wi
Synthesis and x-ray crystal structure of two triorganostannylcobalt complexes
โ Scribed by M. Gielen; I. Vanden Eynde; F. Polet; J. Meunier-Piret; M. van Meerssche
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 485 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0037-9646
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โฆ Synopsis
T h e s y n t h e s i s a n d X -r a y c r y s t a l s t r u c t u r e a n a l y s i s o f t w o t r i o r g a n os t a n n y l c o h a l t c o m p l e x e s ( I ) a n d ( 1 1 ) c o n t a i n i n g a n a s y m m e t r i c t i n a n d a n a s y m m e t r i c c a r b o n a t o m , CH, CO I .. J S y n t h e s i s and s e p a r a t i o n o f r a c e m i c o f YePh(PhUeCHCH2)SnCo(CO) PPh3 ( I ) +
๐ SIMILAR VOLUMES
The mononuclear complexes [Re(CO) 3 (Hpz) 2 Br] (1) and [Re(CO) 3 (py)(Hpz)(pz)] species (6). The analogues of 4 and 6 with Hdmpz, i.e. [Re(CO) 3 (Hdmpz) 2 (dmpz)] ( ) and [Re(CO) 3 (Hdmpz) 2 Br] (2) were obtained by treating [Re(CO) 5 Br] with pyrazole (Hpz) or 3,5-dimethylpyrazole [Re(CO) 3 (py)(H
Reactions of trialkylalanes AlR 3 (R = Me, Et, tBu) and triorganylbismuthanes BiRะ 3 (Rะ = iPr, SiMe 3 ) were performed and the products investigated both in solution and in the solid state. Et 3 Al-Bi(SiMe 3 ) 3 (2), tBu 3 Al-Bi(SiMe 3 ) 3 (3), and tBu 3 Al-Bi(iPr) 3 ( 6) are stable Lewis acid-base
By reacting [Re(CO) 3 (Hpz) 2 (pz)] (Hpz = pyrazole) with characterized in the solid state by single crystal X-ray diffraction analysis and were showed to contain ReโขโขโขMn [Mn(CO) 5 Br] in toluene in the presence of Et 3 N, the dinuclear complex [(CO) 3 Re(pz) 3 Mn(CO) 3 ](Et 3 NH) (1) was interactio