𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and use of a new alkene-functionalized SG1-based alkoxyamine

✍ Scribed by Bernhardt, Claire ;Stoffelbach, François ;Charleux, Bernadette

Book ID
120036491
Publisher
The Royal Society of Chemistry
Year
2011
Tongue
English
Weight
267 KB
Volume
2
Category
Article
ISSN
1759-9954

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Nitroxide-Mediated Polymerization of Met
Nitroxide-Mediated Polymerization of Methyl Methacrylate Using an SG1-Based Alkoxyamine: How the Penultimate Effect Could Lead to Uncontrolled and Unliving Polymerization
✍ Yohann Guillaneuf; Didier Gigmes; Sylvain R. A. Marque; Paul Tordo; Denis Bertin 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB

## Abstract **Summary:** The nitroxide‐mediated polymerization (NMP) of MMA initiated with a new crowded SG1‐based alkoxyamine was performed. Contrary to the results expected after a kinetic analysis (Fischer's diagram), the polymerization of MMA at 45 °C with SG1 showed only partial control and li

Synthesis and reactivity of functionaliz
Synthesis and reactivity of functionalized alkoxyamine initiators for nitroxide-mediated radical polymerization of styrene
✍ Irene Q Li; Daniel M Knauss; Duane B Priddy; Bob A Howell 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB

## Abstract The synthesis and examination of different functionalized (2,2,6,6‐tetramethyl‐1‐piperidinyloxy free radical) TEMPO‐containing alkoxyamine initiators for nitroxide‐mediated radical polymerization of styrene are reported. Initiators with ester and carbonate functional groups were synthes

A New, Efficient and Stereocontrolled Sy
A New, Efficient and Stereocontrolled Synthesis of Trisubstituted Alkenes via Functionalized Acrylic Esters
✍ Dr. Jürgen Rabe; Prof. H. M. R. Hoffmann 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB 👁 2 views

Typical example: (3-Formylpropyl)benzoate 2c (19.2 g, 0.1 mol) was mixed with methyl acrylate 3 (13 g; 14 mL; 0.15 mol). After addition of DABCO (1.6 g, 0.015 mol) the resulting homogeneous mixture was allowed to stand at room temperature until 2c was no longer detectable (cu. 7 days). The remaining