The title 1,Zanhydro sugar (8) was synthesized from D-xylose. The key intermediate for the synthesis was 2-0-acetyl-3,4-di-0-benzyl-@-o-xylopyranosyl fluoride, which was transformed into crystalline 8 by ring closure with potassium tert-butoxide. Comparison of the observed vicinal coupling constants
Synthesis and unusual glycosidic coupling reaction of substituted 2,7-dioxabicyclo[4.1.0]heptanes: 1,2-anhydro-3,4-di-O-benzyl-α-d-fucopyranose
✍ Scribed by Yuguo Du; Fanzuo Kong
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 454 KB
- Volume
- 275
- Category
- Article
- ISSN
- 0008-6215
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