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Synthesis and transformations of acyloxy(chloromethyl)phosphonates and acyloxy(chloromethyl)phosphinates

โœ Scribed by N. A. Khailova; A. A. Shaimardanova; M. A. Pudovik


Book ID
105595047
Publisher
Springer
Year
1998
Tongue
English
Weight
149 KB
Volume
47
Category
Article
ISSN
1573-9171

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The reaction of [di(acyloxy)iodo]benzene with secondary phosphine oxides or H-phosphinates in the presence of primary or secondary amines allows one to obtain phosphinic or phosphonic acids amides in the one-pot process. We take advantage of the strong acylating system DAIB/R 2 P(O)H to phosphinylat