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Synthesis and transannular diels-alder reactions of (E,E,E)-cyclotetradeca-2,8,10-trienones

โœ Scribed by William R. Roush; Joseph S. Warmus; Andrea B. Works


Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
272 KB
Volume
34
Category
Article
ISSN
0040-4039

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Transannular Diels-Alder reaction of the 14-membered (E,E,E)-trienone 9 and a discussion of its high diastereoselectivity based on MM2 transition-state model are presented. Macrocyclic reactions should follow a predictable course in organic synthesesl). if preparations and rapid conformational analy