✦ LIBER ✦

Synthesis and thermolysis of 3-substituted 3-trimethylsilylcyclopropenes

✍ Scribed by Tina L. Arrowood; Steven R. Kass

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 546 KB
Volume: 55
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00276-8

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✦ Synopsis

The synthesis of 3-substituted-3-(trimethylsilyl)cyclopropenes (X = CO2Et, CHO, CN) is described. Their acid sensitivity and thermal stability was probed and the reaction products were identified. In one case, a novel rearrangement to a Dewar furan maybe involved and this pathway was explored via kinetics and computations.

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