Thermal degradations of 4,4Π-diphenylmethane diisocyanate-based thermoplastic polyurethane elastomers were conducted and investigated as functions of heating conditions by using thermogravimetric analysis, ultraviolet-visible (UV-vis) spectroscopy, gel permeation chromatography (GPC), and Fourier tr
Synthesis and thermal studies of block copolymers from NR and MDI-based polyurethanes
β Scribed by Prema Sukumar; V. Jayashree; M. R. Gopinathan Nair; M. N. Radhakrishnan Nair
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 379 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0021-8995
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## Abstract Different multiple hard segment polyurethaneβimide copolymers (MHPUI) were synthesized and characterized. FTIR spectroscopy confirmed the characteristic absorption of the MHPUI copolymer. The difference in the imide group FTIR absorption bands in different MH segment PUI copolymers was
Homopolymers of adipic anhydride (AA) and block copolymers of 1-caprolactone (1-CL) and AA have been synthesized with aluminum triisopropoxide as an initiator. Homopolymerization was studied at 20ΠC in toluene and methylene chloride (CH 2 Cl 2 ). The end-group analysis agrees with a coordination ins