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Synthesis and Thermal Ring Opening of trans-3,4-Disilylcyclobutene

✍ Scribed by Masahiro Murakami; Munehiro Hasegawa

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 238 KB
Volume: 43
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200460144

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✦ Synopsis

In the reaction described by M. Murakami and M. Hasegawa on the following pages, the electronic effects are so dramatic that the sterically hindered substrate prefers to react by a more crowded pathway. This reaction will provide organic chemistry textbooks with a prime example of systems in which electronic effects are dominant over steric effects in determining the stereochemical outcome of a reaction.

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