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Synthesis and thermal rearrangement of homopentafulvalenes

โœ Scribed by Hafner, Klaus; Thiele, Georg F.


Book ID
127117506
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
750 KB
Volume
107
Category
Article
ISSN
0002-7863

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5-Diazomethyl-4-methoxycarb9nyltriazoles are capable of undergoing ring-degenerate rearrangements (19 + 0) when a strong electron-withdrawing substituent (e.g. pnitrophenyl or o.p-d%nitrophenyl) is located at the N-l position. Whereas the unrearranged diaeomethyltrlazole 198 decomposes thermally in