Synthesis and Thermal Isomerization of Carboxylic and Phosphonic α-Aminoesters Substituted With a Triazole Ring
✍ Scribed by Achamlale, S.; Mabrouk, H.; Elachqar, A.; El Hallaoui, A.; El Hajji, S.; Alami, A.; Bellan, J.; Mazières, M. R.; Wolf, J. G.; Pierrot, M.
- Book ID
- 120407807
- Publisher
- Taylor and Francis Group
- Year
- 2007
- Tongue
- English
- Weight
- 331 KB
- Volume
- 182
- Category
- Article
- ISSN
- 1042-6507
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## Abstract Diastereomeric [(3__S__)‐5α]‐ and [(3__R__)‐5α]‐2′,2′‐dichlorospiro‐[cholestane‐3,1′‐cyclobutan]‐3′‐ones (1 and 2), prepared by cycloaddition reaction of dichloroketene with 3‐methylene‐5α‐cholestane, served as starting material for the synthesis of the related spirane derivatives. Thus