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Synthesis and Theoretical Investigation of a 1,8-Bis(bis(diisopropylamino)cyclopropeniminyl)naphthalene Proton Sponge Derivative

✍ Scribed by Belding, Lee; Dudding, Travis


Book ID
121648129
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
806 KB
Volume
20
Category
Article
ISSN
0947-6539

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1,8-Bis(tetramethylguanidino)naphthalene
✍ Volker Raab; Jennifer Kipke; Ruth M. Gschwind; Jörg Sundermeyer 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 399 KB 👁 1 views

1,8-Bis(tetramethylguanidino)naphthalene (TMGN, 1) is a new, readily accessible, and stable ™proton sponge∫ with an experimental pK BH value of 25.1 in MeCN, which is nearly seven orders of magnitude higher in basicity than the classical proton sponge 1,8-bis(dimethylamino)-naphthalene (DMAN). Becau