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Synthesis and the crystal and electronic structure of Hg4AsI5

✍ Scribed by O. S. Oleneva; T. A. Shestimerova; A. V. Olenev; E. V. Dikarev; A. V. Shevelkov


Publisher
Springer
Year
2006
Tongue
English
Weight
289 KB
Volume
55
Category
Article
ISSN
1573-9171

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Colorless crystals of diamagnetic \(\mathrm{InCdBr}_{3}\) are synthesized from elemental \(\mathrm{Cd}\) in an \(\mathrm{InBr}_{3}\) melt. The new phase crystallizes in the orthorhombic \(\mathrm{NH}_{4} \mathrm{CdCl}_{3}\) structure type \((a=944.7(2) \mathrm{pm}, b=\) 410.47(8) pm, \(c=1545.5(3) \