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Synthesis and synthetic applications of 2-amino-3-halo-1-oxypropanes

✍ Scribed by Matthias D'hooghe; Norbert De Kimpe

Book ID
118501446
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
702 KB
Volume
64
Category
Article
ISSN
0040-4020

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✍ Shengming Ma; Guangwei Wang 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 239 KB

1-Aryl-3-halo-1,3-dienes were prepared from the sequential addition-elimination reaction of 1-aryl-2,3-allenols with LiX (X=Br, Cl) in HOAc in moderate to good yields. Here the aromatic substituent is crucial to this interesting transformation since no reaction was observed with 1-alkyl or perfluoro